Carborane‐Induced Excimer Emission of Severely Twisted Bis‐ o ‐Carboranyl Chrysene

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چکیده

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Selective formation of twisted intramolecular charge transfer and excimer emissions on 2,7-bis(4-diethylaminophenyl)-fluorenone by choice of solvent.

We designed and synthesized a donor-acceptor-donor dye consisting of a 2,7-disubstituted fluorenone with diethylaminophenyl moieties present as strong electron donating groups. Switching between twisted intramolecular charge transfer (TICT) emission and excimer emission was achieved, with no ground state changes, by simply changing the solvent used. In a nonpolar solvent, excimer emission was o...

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In the mol-ecule of the title compound, C(17)H(18)N(2)O(2), the dihedral angle between the aromatic rings is 74.26 (3)°. The oxime units are oriented at dihedral angles of 7.66 (3) and 33.06 (3)° with respect to the adjacent rings, and they have E configurations about the C=N bonds.

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Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ3 O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate

The title complex, [Ca(C(27)H(30)N(4)O(3))(2)](ClO(4))(2)·2CH(3)CN, is composed of centrosymmetric (CaL(2))(2+) cations [L = tris-(2-hy-droxy-benzoyl-amino-eth-yl)amine = H(3)saltren], uncoordin-ated perchlorate anions and acetonitrile solvent mol-ecules. The calcium ion is six-coordinated and is bonded to all phen-oxy O atoms from both zwitterionic saltren mol-ecules. There are strong intra-mo...

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2018

ISSN: 0044-8249,1521-3757

DOI: 10.1002/ange.201805967